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A12975 3,4-(Methylenedioxy)aniline, 98+%

CAS Number
14268-66-7
Synonyms
5-Amino-1,3-benzodioxole
1,3-Benzodioxol-5-amine

Stock No. Size Price ($) Quantity Availability
A12975-09 10g 27.20
A12975-18 50g 95.00
A12975-30 250g 379.00
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3,4-(Methylenedioxy)aniline, 98+%

MDL
MFCD00005832
EINECS
238-161-6

Chemical Properties

Formula
C7H7NO2
Formula Weight
137.14
Melting point
40-45°
Boiling Point
144°/16mm
Flash Point
142°(287°F)
Storage & Sensitivity
Air Sensitive. Light Sensitive. Ambient temperatures.
Solubility
Slightly soluble in water.

Applications

3,4-(Methylenedioxy)aniline is an pharmaceutically important aniline derivative. It undergoes N-alkylation with cyclic secondary alkylamines in the presence of Shvo catalyst to yield N-arylpyrrolidines. 3,4-(Methylenedioxy)aniline was used in the synthesis of γ-glutamylanilides.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible to strong acids, acid chlorides, acid anhydrides. Air & Light Sensitive. Stable under recommended storage conditions.

Literature References

SJ Tu.; XD Cao.; WJ Hao.; XH Zhang .; S Yan. An efficient and chemoselective synthesis of benzo [e][1, 4] thiazepin-2 (1 H, 3 H, 5 H)-ones via a microwave-assisted multi-component reaction in water. Organic & Biomolecular Chemistry. 20097, (3) , 557-563.

MJ Luzzio.; JM Besterman.; DL Emerson. Synthesis and antitumor activity of novel water soluble derivatives of camptothecin as specific inhibitors of topoisomerase I. J. Med. Chem. 199538, (3) , 395-401.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
4919
Harmonized Tariff Code
2932.99
TSCA
Yes

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