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A13026 Nickel(II) acetate tetrahydrate, 98+%

CAS Number
6018-89-9
Synonyms
Acetic acid nickel(II) salt

Stock No. Size Price ($) Quantity Availability
A13026-22 100g 26.90
A13026-36 500g 60.60
A13026-0E 2500g 246.00
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Nickel(II) acetate tetrahydrate, 98+%

MDL
MFCD00066973
EINECS
206-761-7

Chemical Properties

Formula
Ni(CH3COO)2•4H2O
Formula Weight
248.84 (176.79anhy)
Melting point
dec.
Density
1.744
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water and methanol. Insoluble in diethyl ether and n-octanol.

Applications

Nickel(II) acetate tetrahydrate is used in electroplating. It is also used in the preparation of polynuclear-nickel polyoxotungstate cluster compounds, which are used in designing molecular magnets. Further, it is used as a catalyst and mordant for dyeing textiles, as a sealant for anodized aluminum and to make other nickel compounds.

Notes

Hygroscopic. Incompatible with oxidizing agents, strong acids and strong bases.

Literature References

In combination with NaH and the Na derivative of 3-Hydroxy-1-methyl­piperidine, L10829 , can be used for desufurization of thioethers, showing dramatic rate enhancement compared with other systems: Tetrahedron Lett., 39, 8987 (1998).

Das, M.; Harms, K.; Ghosh, B. N.; Rissanen, K.; Chattopadhyay, S. Bis(?-tetrazolato-NN') bridged dinuclear nickel(II) Schiff base complexes: Tandem synthesis, structure and self assembly. Polyhedron 2015, 87, 286-292.

Sivakumar, P.; Nayak, P. K.; Markovsky, B.; Aurbach, D.; Gedanken, A. Sonochemical synthesis of LiNi0.5Mn1.5O4 and its electrochemical performance as a cathode material for 5V Li-ion batteries. Ultrason. Sonochem. 2015, 26, 332-339.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H317-H332-H334-H335-H341-H350i-H360D-H372

Harmful if swallowed. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. May cause cancer by inhalation. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P260-P264b-P270-P271-P272-P280g-P281-P285-P301+P312-P302+P352-P304+P340-P308+P313-P330-P333+P313-P342+P311-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation or rash occurs: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6499
Beilstein
3730764
Harmonized Tariff Code
2915.29
TSCA
Yes
RTECS
QR6126000

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