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6018-89-9 - Nickel(II) acetate tetrahydrate, 98+% - Acetic acid nickel(II) salt - A13026 - Alfa Aesar

A13026 Nickel(II) acetate tetrahydrate, 98+%

CAS Number
6018-89-9
Synonyms
Acetic acid nickel(II) salt

Size Price ($) Quantity Availability
100g 23.04
500g 57.37
2500g 210.60
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Nickel(II) acetate tetrahydrate, 98+%

MDL
MFCD00066973
EINECS
206-761-7

Chemical Properties

Formula
Ni(CH3COO)2•4H2O
Formula Weight
248.84 (176.79anhy)
Melting point
dec.
Density
1.744
Solubility
Soluble in water and methanol. Insoluble in diethyl ether and n-octanol.

Applications

Nickel(II) acetate tetrahydrate is used in electroplating. It is also used in the preparation of polynuclear-nickel polyoxotungstate cluster compounds, which are used in designing molecular magnets. Further, it is used as a catalyst and mordant for dyeing textiles, as a sealant for anodized aluminum and to make other nickel compounds.

Notes

Hygroscopic. Incompatible with oxidizing agents, strong acids and strong bases.

Literature References

In combination with NaH and the Na derivative of 3-Hydroxy-1-methyl­piperidine, L10829 , can be used for desufurization of thioethers, showing dramatic rate enhancement compared with other systems: Tetrahedron Lett., 39, 8987 (1998).

Das, M.; Harms, K.; Ghosh, B. N.; Rissanen, K.; Chattopadhyay, S. Bis(?-tetrazolato-NN') bridged dinuclear nickel(II) Schiff base complexes: Tandem synthesis, structure and self assembly. Polyhedron 2015, 87, 286-292.

Sivakumar, P.; Nayak, P. K.; Markovsky, B.; Aurbach, D.; Gedanken, A. Sonochemical synthesis of LiNi0.5Mn1.5O4 and its electrochemical performance as a cathode material for 5V Li-ion batteries. Ultrason. Sonochem. 2015, 26, 332-339.

GHS Hazard and Precautionary Statements

Hazard Statements: H334-H350-H360-H372-H317-H341-H400-H410-H302-H332

May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause cancer. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. May cause an allergic skin reaction. Suspected of causing genetic defects. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Harmful if inhaled.

Precautionary Statements: P260-P285-P201-P261-P273-P280-P281-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,6499
Beilstein
3730764
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2915.29
TSCA
Yes
RTECS
QR6126000

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