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A13028 4-Fluorobenzonitrile, 99%

CAS Number
1194-02-1
Synonyms
4-Cyanofluorobenzene

Stock No. Size Price ($) Quantity Availability
A13028-06 5g 22.00
A13028-14 25g 68.30
A13028-22 100g 245.00
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4-Fluorobenzonitrile, 99%

MDL
MFCD00001812
EINECS
214-784-9

Chemical Properties

Formula
C7H4FN
Formula Weight
121.11
Melting point
34-37°
Boiling Point
186-188°
Flash Point
65°(149°F)
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

4-Fluorobenzonitrile is used as chemical intermediate, solvent for perfumes and pharmaceuticals, stabilizer for chlorinated solvents, HPLC analysis, catalyst and component of transition-metal complex catalysts.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Eric J.Schelter; David E.Morris; Brian L.Scott; Jaqueline L.Kiplinger. Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(IV) tetraazametallacycle. Chemical Communications. 2007, (10),1029-1031

 

A.Muthukrishnan; M.V.Sangaranarayanan. Electrochemical reduction of carbon-fluorine bond in 4-fluorobenzonitrile - Mechanistic analysis employing Marcus-Hush quadratic activation-driving force relation. Chemical Physics Letters. 2007, 446, (4-6),297-303

Displacement of the fluoro-substituent by phenols or thiophenols, to give the corresponding diaryl ethers or thioethers, is promoted by KF on alumina in the presence of 18-crown-6: J. Org. Chem., 58, 3229 (1993).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H332-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2041517
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
DI4368500

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