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1194-02-1 - 4-Fluorobenzonitrile, 99% - 4-Cyanofluorobenzene - A13028 - Alfa Aesar

A13028 4-Fluorobenzonitrile, 99%

CAS Number
1194-02-1
Synonyms
4-Cyanofluorobenzene

Size Price ($) Quantity Availability
5g 20.50
25g 64.58
100g 231.75
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4-Fluorobenzonitrile, 99%

MDL
MFCD00001812
EINECS
214-784-9

Chemical Properties

Formula
C7H4FN
Formula Weight
121.11
Melting point
34-37°
Boiling Point
186-188°
Flash Point
65°(149°F)
Solubility
Insoluble in water.

Applications

4-Fluorobenzonitrile is used as chemical intermediate, solvent for perfumes and pharmaceuticals, stabilizer for chlorinated solvents, HPLC analysis, catalyst and component of transition-metal complex catalysts.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Eric J.Schelter; David E.Morris; Brian L.Scott; Jaqueline L.Kiplinger. Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(IV) tetraazametallacycle. Chemical Communications. 2007, (10),1029-1031

 

A.Muthukrishnan; M.V.Sangaranarayanan. Electrochemical reduction of carbon-fluorine bond in 4-fluorobenzonitrile - Mechanistic analysis employing Marcus-Hush quadratic activation-driving force relation. Chemical Physics Letters. 2007, 446, (4-6),297-303

Displacement of the fluoro-substituent by phenols or thiophenols, to give the corresponding diaryl ethers or thioethers, is promoted by KF on alumina in the presence of 18-crown-6: J. Org. Chem., 58, 3229 (1993).

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280h-P305+P351+P338-P309+P311

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.

Other References

Beilstein
2041517
Harmonized Tariff Code
2926.90
TSCA
Yes
RTECS
DI4368500

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