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A13044 Aluminum sec-butoxide, 97%

CAS Number
2269-22-9
Synonyms
Aluminum tri-sec-butoxide

Stock No. Size Price ($) Quantity Availability
A13044-22 100g 36.80
A13044-36 500g 101.00
A13044-0E 2500g 430.00
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Aluminum sec-butoxide, 97%

MDL
MFCD00009327
EINECS
218-871-2

Chemical Properties

Formula
C12H27AlO3
Formula Weight
246.32
Boiling Point
200-206°/30mm
Flash Point
27°(82°F)
Density
0.967
Refractive Index
1.4390
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Miscible with alcohol, isopropyl alcohol and toluene.

Applications

Aluminum sec-butoxide is used to prepare photosensitive alumina gel films. It is also used in the preparation of microporous crystalline aluminophosphate AlPO-41 and alumina mesoporous material. It is used as a gelling agent of paint and ink and water repellent substance of wood. Further, it acts as an active catalyst and reducer of aldehydes and ketones. In addition to this, it is used to make high-surface-area alumina using 2,4-pentanedione as a chelating agent.

Notes

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong acids, metals and halogens.

Literature References

Limwanich, W.; Punyodom, W.; Kungwan, N.; Meepowpan, P. DSC Kinetics Analysis for the Synthesis of Three-Arms Poly(epsilon-caprolactone) Using Aluminum Tri-sec-Butoxide as Initiator. Int. J. Chem. Kinet. 2015, 47 (11), 734-743.

Ishihara, A.; Imai, T.; Hashimoto, T.; Nasu, H. Hydrothermal gasification of phenol water on novel carbon-supported Ni catalysts prepared by the sol-gel method using tartaric acid and alminum tri-sec-butoxide. Fuel Process. Technol. 2015, 136, 34-40.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H319-H335-H336

Flammable liquid and vapour. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P337+P313-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3910908
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.19
TSCA
Yes

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