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A13049 2,4,6-Trimethylaniline, 98%

CAS Number
88-05-1
Synonyms
Mesidine
2-Aminomesitylene

Stock No. Size Price ($) Quantity Availability
A13049-22 100g 38.10
A13049-36 500g 144.00
A13049-0E 2500g 633.00
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2,4,6-Trimethylaniline, 98%

MDL
MFCD00007740
EINECS
201-794-3

Chemical Properties

Formula
C9H13N
Formula Weight
135.21
Melting point
-5°
Boiling Point
232-234°
Flash Point
96°(204°F)
Density
0.962
Refractive Index
1.5510
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly miscible with carbon tetrachloride. Immiscible with water.

Applications

2,4,6-Trimethylaniline is useful for the preparation of Grubbs' catalyst. It is used as a precursor to dyes. It undergoes condensation reaction with glyoxal to prepare glyoxal-bis(mesitylimine). It is also involved in the preparation of 1,3-diketimines ligands by condensation with 1,3-diketones. Further, it is used for the production of Acid Blue 129 dye, which is useful in histochemistry studies. In addition to this, it serves as a building block to various bulky ligands.

Notes

Incompatible with strong oxidizing agents.

Literature References

Samanta, R. C.; Yamamoto, H. Selective Halogenation Using an Aniline Catalyst. Chem. Eur. J. 2015, 21 (34), 11976-11979.

Kalden, D.; Krieck, S.; Görls, H.; Westerhausen, M. 1,3-Bis(2,4,6-trimethylphenyl)triazenides of potassium, magnesium, calcium, and strontium. Dalton Trans. 2015, 44 (17), 8089-8099.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H373

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P262-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P311-P312-P314-P330-P361-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. Rinse mouth. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
636559
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.49
TSCA
Yes
RTECS
BZ0700000

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