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A13058 Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol

CAS Number
Vinyl cyanide

Stock No. Size Price ($) Quantity Availability
A13058-AE 100ml 16.40
A13058-AP 500ml 25.30
A13058-0F 2500ml 74.60
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Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol


Chemical Properties

Formula Weight
Melting point
Boiling Point
Flash Point
Refractive Index
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Miscible with isopropanol, ethanol, ether, acetone, water, carbon tetrachloride, ethyl acetate, toluene and benzene.


Acrylonitrile acts as a monomer used in the production of polyacrlonitrile plastics, adhesives and synthetic rubber. It is also used for the synthesis of copolymers such as styrene-acrylonitrile, acrylonitrile butadiene styrene, acrylonitrile styrene acrylate. It is involved in the preparation of adiponitrile by dimerization, which finds application in polyamide synthesis. It acts as a precursor to acrylamide and acrylic acid. It is used as dienophile in Diels-Alder reactions. It acts as a chemical intermediate in the synthesis of antioxidants, active pharmaceutical ingredients, dyes, and surface-active agents. Further, it is utilized for the preparation of acrylic fibers, resins and nitrile rubbers. In addition to this, it serves as a fumigant for food commodities, flour milling, and bakery food processing equipment.


Light sensitive. Incompatible with oxidizing agents, acids, alkalis, metals, bromine, peroxides and copper.

Literature References

The Stetter reaction (conjugate addition of aryl aldehydes) catalyzed by CN-, is exemplified by the addition of pyridine-3-carboxaldehyde to acrylonitrile to give 4-oxo-4-(3-pyridyl)butyronitrile: Org. Synth. Coll., 6, 866 (1988). See also 3-Benzyl-5-(2-hydroxyethyl)-4-methyl­thiazolium chloride, L08750.

Free radical alkylation, acylation and arylation reactions also occur in the presence of t-butyl hydroperoxide and a Cu(II) catalyst: J. Chem. Soc., Chem. Commun., 1399 (1995). Several other free radical procedures have been reported involving intramolecular homolytic aromatic substitution to give carbocyclic and heterocyclic systems: Tetrahedron Lett., 36, 4307 (1995):

The reaction is also applicable to acrylate esters and vinyl ketones; with acrylonitrile and phenoxyacetic acid, tetrahydrobenzopyran-4-carbonitrile is obtained in 41% yield.

Dai, Y.; Song, Y.; Tu, X.; Jiang, Y.; Yuan, Y. Sequential shape-selective adsorption and photocatalytic transformation of acrylonitrile production wastewater. Water Res. 2015, 85, 216-225.

Pan, X.; Lamson, M.; Yan, J.; Matyjaszewski, K. Photoinduced Metal-Free Atom Transfer Radical Polymerization of Acrylonitrile. ACS Macro Lett. 2015, 4 (2), 192-196.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H301+H311+H331-H315-H317-H318-H335-H350-H361

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause respiratory irritation. May cause cancer. Suspected of damaging fertility or the unborn child.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P264b-P270-P271-P272-P280g-P281-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P311-P312-P330-P333+P313-P363-P37

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation or rash occurs: Wash contaminated clothing before reuse.

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


  • A13128

    Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol
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  • B24815

    2-Hydroxyethyl acrylate, 97%, stab. with 200-300ppm 4-methoxyphenol
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