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615-43-0 - 2-Iodoaniline, 98+% - A13059 - Alfa Aesar

A13059 2-Iodoaniline, 98+%

CAS Number
615-43-0
Synonyms

Size Price ($) Quantity Availability
5g 28.64
25g 110.21
50g 190.72
100g 298.40
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2-Iodoaniline, 98+%

MDL
MFCD00007680
EINECS
210-426-0

Chemical Properties

Formula
C6H6IN
Formula Weight
219.03
Melting point
53-57°
Flash Point
>110°(230°F)
Sensitivity
Light Sensitive
Solubility
Insoluble in water.

Applications

2-Iodoaniline is used as an intermediate in organic synthesis.

Notes

It is sensitive to light. Incompatible with oxidizing agents.

Literature References

Gozen Bereket; Evrim Hur; Yucel Sahin. Electrodeposition of polyaniline, poly(2-iodoaniline), and poly(aniline-co-2-iodoaniline) on steel surfaces and corrosion protection of steel. Applied Surface Science. 2005, 252, (5),1233-1244

 

Qiuping Ding; Banpeng Cao; Xianjin Liu; Zhenzhen Zongand; Yi-Yuan Peng. Synthesis of 2-aminobenzothiazole via FeCl3-catalyzed tandem reaction of 2-iodoaniline with isothiocyanate in water. Green Chemistry. 2010, (9),1607-1610

Quinolines may be synthesized by Pd-catalyzed reaction with allyl alcohols: Tetrahedron Lett., 32, 569 (1991).

Reacts with unsymmetrical acetylenes in the presence of Palladium(II)­ acetate, 10516, to give indoles substituted at the 2- and/or 3-positions: J. Am. Chem. Soc., 113, 6689 (1991):

Under similar conditions, ketones with an ɑ-methylene group also give indole derivatives: J. Org. Chem., 62, 2676 (1997).

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H332-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2204899
Harmonized Tariff Code
2921.42
TSCA
Yes

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