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A13068 Cyclobutanone, 98%, stab. with ca 0.01% BHT

CAS Number
1191-95-3
Synonyms

Stock No. Size Price ($) Quantity Availability
A13068-03 1g 71.40
A13068-06 5g 231.00
A13068-14 25g 997.00
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Cyclobutanone, 98%, stab. with ca 0.01% BHT

MDL
MFCD00001332
EINECS
214-745-6

Chemical Properties

Formula
C4H6O
Formula Weight
70.09
Melting point
-51°
Boiling Point
97-99°
Flash Point
10°(50°F)
Density
0.935
Refractive Index
1.4210
Storage & Sensitivity
May form a Precipitate. Ambient temperatures.
Solubility
Immiscible with water.

Applications

Cyclobutanone is used in preparation of cyclobutane derivatives. It is used as a starting material for aminocyclobutanecarboxylic acid through sulfonyloxiranes. It is also used to prepare dihydro-furan-2-one in presence of polystyrene-bound phenylselenic acid as catalyst. Further, it is involved in the photochemical synthesis of nucleoside analogues such as bicyclic nucleosides and isonucleosides.

Notes

Store in a cool place. Incompatible with strong oxidizing agents, strong bases and strong reducing agents.

Literature References

Lumbroso, A.; Catak, S.; Sulzer-Mosse, S.; Mesmaeker, A. D. Efficient access to functionalized cyclobutanone derivatives using cyclobuteniminium salts as highly reactive Michael acceptors. Tetrahedron Lett. 2015, 56 (19), 2397-2401.

Souillart, L.; Cramer, N. Regiodivergent Cyclobutanone Cleavage: Switching Selectivity with Different Lewis Acids. Chem. Eur. J. 2015, 21 (5), 1863-1867.

GHS Hazard and Precautionary Statements

Hazard Statements: H225

Highly flammable liquid and vapour.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1560289
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2914.29
TSCA
Yes

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