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1271-55-2 - 1-Acetylferrocene, 97% - (Acetylcyclopentadienyl)cyclopentadienyliron - Ferrocenyl methyl ketone - A13078 - Alfa Aesar

A13078 1-Acetylferrocene, 97%

CAS Number
1271-55-2
Synonyms
(Acetylcyclopentadienyl)cyclopentadienyliron
Ferrocenyl methyl ketone

Size Price ($) Quantity Availability
5g 23.69
25g 94.76
100g 329.60
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1-Acetylferrocene, 97%

MDL
MFCD00001432
EINECS
215-043-2

Chemical Properties

Formula
C12H12FeO
Formula Weight
228.07
Melting point
79-86°
Boiling Point
160-163°/4mm
Solubility
Insoluble in water. Soluble in most organic solvents.

Applications

1-Acetylferrocene was originally used in military or space field as an additive in rocket propellant, to promote the burning rate. Its ferrocenyl derivative has wide applications to biological and medical fields such as ferrocene-modified beta-lactam because of its physiological activity of anti-malarial, anti-tumor, bactericidal, anti-inflammatory, treatment of anemia, inhibition of enzymatic activity and so on by virtue of its unique structure and diverse properties.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

R.V.Singh; S.C.Joshi; Anita Gajraj; Pooja Nagpal. Studies of biologically potent organotin(IV) and organosilicon(IV) complexes of a sulfur donor ligand derived from 1-acetylferrocene. Applied Organometallic Chemistry. 2002, 16, (12),713-720

 

A procedure for the conversion of methyl ketones to terminal acetylenes is exemplified by reaction with POCl3 - DMF to give (2-formyl-1-chlorovinyl)ferrocene which, by elimination with NaOH, affords ethynylferrocene: J. Organomet. Chem., 6, 173 (1966); Org. Synth. Coll., 9, 411 (1998).

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310

Fatal if swallowed. Fatal in contact with skin.

Precautionary Statements: P262-P280-P301+P310-P361-P302+P350-P310-P363-P321-P405-P501a

Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Gently wash with plenty of soap and water. Wash contaminated clothing before reuse. Specific treatment (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
OB3700000

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