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A13113 Chlorodimethylsilane, 97%

CAS Number
1066-35-9
Synonyms
Dimethylchlorosilane

Stock No. Size Price ($) Quantity Availability
A13113-AD 50ml 37.90
A13113-AK 250ml 164.00
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Chlorodimethylsilane, 97%

MDL
MFCD00000495
EINECS
213-912-0

Chemical Properties

Formula
C2H7ClSi
Formula Weight
94.62
Melting point
-111°
Boiling Point
34-36°
Flash Point
-28°(-18°F)
Density
0.869
Refractive Index
1.3830
Storage & Sensitivity
Keep Cold. Moisture Sensitive.
Solubility
Miscible with organic solvents.

Applications

Chlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides.

Notes

It is incompatible with strong oxidizing agents, strong acids, strong bases, metals and water.

Literature References

Chen, H.; Zhang, S.; Kong, J. Topological analysis and intramolecular cyclic feature evaluation of polymers derived from Am + Bn step-growth polymerization. Polym. Chem. 2015, 6 (6), 909-916.

Jebors, S.; Ciccione, J.; Al-Halifa, S.; Nottelet, B.; Enjalbal, C.; Kadmi, C. M.; Amblard, M.; Mendi, A.; Martinez, J.; Subra, G. A New Way to Silicone-Based Peptide Polymers. Angew. Chem. Int. Ed. 2015, 54 (12), 3778-3782.

GHS Hazard and Precautionary Statements

Hazard Statements: H224-H314-H335

Extremely flammable liquid and vapour. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1633434
Hazard Class
3
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
Yes

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