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Methyl acrylate is a monomer used in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. It is involved in the production of acrylate fiber, which is used to weave synthetic carpets. It plays an important role as a reagent in the synthesis of pharmaceutical intermediates and alfa ω-dicarboxylic acid esters. It is a good nucleophile and a michael acceptor to prepare polyamidoamine (PAMAM) dendrimers.
Dai, S.; Sui, X.; Chen, C. Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate. Angew. Chem. Int. Ed. 2015, 54 (34), 9948-9953.
Xia, G.; Jiang, X.; Zhou, L.; Liao, Y.; Wang, H.; Pu, Q.; Zhou, J. Synergic effect of methyl acrylate and N-cetylpyridinium bromide in N-cetyl-3-(2-methoxycarbonylvinyl) pyridinium bromide molecule for X70 steel protection. Corros. Sci. 2015, 94, 224-236.
Hazard Statements: H225-H302-H312-H332-H315-H319-H317-H335
Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause respiratory irritation.
Precautionary Statements: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.