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A13128 Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol

CAS Number
96-33-3
Synonyms
Acrylic acid methyl ester
Methyl propenoate

Stock No. Size Price ($) Quantity Availability
A13128-AE 100ml 17.20
A13128-AP 500ml 31.30
A13128-0F 2500ml 72.00
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Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol

MDL
MFCD00008627
EINECS
202-500-6

Chemical Properties

Formula
CH2=CHCO2CH3
Formula Weight
86.09
Melting point
-75°
Boiling Point
79-81°
Flash Point
-3°(26°F)
Density
0.956
Refractive Index
1.4030
Storage & Sensitivity
Keep Cold. Light Sensitive.
Solubility
Miscible with water.

Applications

Methyl acrylate is a monomer used in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. It is involved in the production of acrylate fiber, which is used to weave synthetic carpets. It plays an important role as a reagent in the synthesis of pharmaceutical intermediates and alfa ω-dicarboxylic acid esters. It is a good nucleophile and a michael acceptor to prepare polyamidoamine (PAMAM) dendrimers.

Notes

Light sensitive. Incompatible with oxidizing agents and peroxides.

Literature References

Dai, S.; Sui, X.; Chen, C. Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate. Angew. Chem. Int. Ed. 2015, 54 (34), 9948-9953.

Xia, G.; Jiang, X.; Zhou, L.; Liao, Y.; Wang, H.; Pu, Q.; Zhou, J. Synergic effect of methyl acrylate and N-cetylpyridinium bromide in N-cetyl-3-(2-methoxycarbonylvinyl) pyridinium bromide molecule for X70 steel protection. Corros. Sci. 2015, 94, 224-236.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H312-H315-H317-H319-H331-H335

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic if inhaled. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P272-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P311-P312-P330-P333+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6011
Beilstein
605396
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2916.12
TSCA
Yes
RTECS
AT2800000

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