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1,10-Phenanthroline, anhydrous is used as a chelating agent, used as bidendate nitrogen ligands in Heck type reactions as an alternative to phospine ligands. It is widely used as an indicator for alkyllithium reagents and an inhibitor of metallopeptidase enzymes. It is also used in the analysis formulations in end-user industries like food, beverage and pharmaceuticals.
For use as bidentate nitrogen ligands in Heck type reactions as an alternative to phosphine ligands, see: Synlett., 11, 871 (1992).
Indicator for titration of organolithium reagents, giving red charge-transfer complexes, and also in the titration of Grignard reagents: J. Organomet. Chem., 9, 165 (1967); Org. Synth. Coll., 9, 350, 653, 733 (1998).
Reviews: 1,10-Phenanthroline: a versatile ligand: Chem. Soc. Rev., 23, 327 (1994); Coordination compounds as synthetic building blocks: Synlett, 1043 (2002).
Petrov, E. G.; Marchenko, A.; Kapitanchuk, O. L.; Katsonis, N.; Fichou, D. Conductance Mechanism in a Linear Non-Conjugated Trimethylsilyl-Acetylene Molecule: Tunneling Through Localized States. Spectrochim. Acta, Part A 2015, 147 31-42.
Hazard Statements: H301
Toxic if swallowed.
Precautionary Statements: P264-P270-P301+P310a-P321-P405-P501a
Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER/doctor Specific treatment (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.