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5344-90-1 - 2-Aminobenzyl alcohol, 98% - 2-(Hydroxymethyl)aniline - A13180 - Alfa Aesar

A13180 2-Aminobenzyl alcohol, 98%

CAS Number
5344-90-1
Synonyms
2-(Hydroxymethyl)aniline

Size Price ($) Quantity Availability
10g 25.94
50g 77.10
250g 312.80
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2-Aminobenzyl alcohol, 98%

MDL
MFCD00007749
EINECS
226-293-7

Chemical Properties

Formula
C7H9NO
Formula Weight
123.16
Melting point
81-84°
Boiling Point
160°/10mm
Solubility
Very soluble in water.

Applications

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

Notes

Store at room temperature. Incompatible with oxidizing agents.

Literature References

Chan Sik Cho.; Bok Tae Kim.; Tae-Jeong Kim.; Sang Chul Shim. Ruthenium-catalysed oxidative cyclisation of 2-aminobenzyl alcohol with ketones: modified Friedlaender quinoline synthesis.Chem. Commun. 2001, (24),2576-2577 .

Chan Sik Cho.; Bok Tae Kim.; Heung-Jin Choi.; Tae-Jeong Kim.; Sang Chul Shim. Ruthenium-catalyzed oxidative coupling and cyclization between 2-aminobenzyl alcohol and secondary alcohols leading to quinolines. Tetrahedron. 2003, 59 (40),7997-8002 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1072211
Harmonized Tariff Code
2922.19
TSCA
Yes
RTECS
DN3155000

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