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589-92-4 - 4-Methylcyclohexanone, 98+% - A13186 - Alfa Aesar

A13186 4-Methylcyclohexanone, 98+%

CAS Number
589-92-4
Synonyms

Size Price ($) Quantity Availability
25g 28.53
100g 73.54
500g 251.94
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4-Methylcyclohexanone, 98+%

MDL
MFCD00001643
EINECS
209-665-3

Chemical Properties

Formula
C7H12O
Formula Weight
112.17
Melting point
-41°
Boiling Point
169-171°
Flash Point
48°(118°F)
Density
0.914
Refractive Index
1.4450
Solubility
Not miscible in water.

Applications

4-Methylcyclohexanone was used in the synthesis of the pinguisane-type sesquiterpenoid acutifolone A, in racemic form. It is used as intermediates of CCNU and it can be also be used as a solvent.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Ming-Tsang Hsieh; Hsing-Jang Liu; Tai Wei Ly; Kak-Shan Shia. A concise total synthesis of (+/-)-acutifolone A. Organic & Biomolecular Chemistry. 2009, 7, (16),3285-3290

 

William Agosta; William L.Shreiber. Specificity of hydrogen transfer in photolysis of 3- and 4-methylcyclohexanone. J. Am. Chem. Soc. 1971, 93, (16),3947-3952

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302

Flammable liquid and vapour. Harmful if swallowed.

Precautionary Statements: P210-P280-P240-P241-P233-P242-P303+P361+P353-P301+P312-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Keep container tightly closed. Use only non-sparking tools. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
506746
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2914.22
TSCA
Yes
RTECS
GW1750200

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