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610-97-9 - Methyl 2-iodobenzoate, 98% - 2-Iodobenzoic acid methyl ester - A13204 - Alfa Aesar

A13204 Methyl 2-iodobenzoate, 98%

CAS Number
610-97-9
Synonyms
2-Iodobenzoic acid methyl ester

Size Price ($) Quantity Availability
10g 27.19
50g 89.82
250g 303.30
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Methyl 2-iodobenzoate, 98%

MDL
MFCD00016351
EINECS
210-243-6

Chemical Properties

Formula
C8H7IO2
Formula Weight
262.05
Boiling Point
274°
Flash Point
>110°(230°F)
Density
1.730
Refractive Index
1.6040
Sensitivity
Light Sensitive
Solubility
Insoluble in water.

Applications

2-Iodobenzoic Acid, methyl ester; 2-Iodobenzoic Acid is a starting material for the preparation of iodosobenzoate, selectivity and environment management. Trivalent iodine compounds perform mild oxidations, oxidative couplings, special iodinations and acetoxylations. Iodobenzoates are used as anti-infective, contraceptive agent and x-ray contrast medium for diagnostic radiology.

Notes

Light sensitive. Store at room temperature. Incompatible with oxidizing agents.

Literature References

Ronald Grigg.; Tossapol Khamnaen.; Shuleewan Rajviroongit.; Visuvanathar Sridharan. Synthesis of N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones via a palladium-catalysed three-component process. Tetrahedron Lett. 2002, 43 (14),2601-2603 .

Esther C.Y. Woon.; Archana Dhami.; Mary F. Mahon.; Michael D. Threadgill. 5-Nitroisocoumarins from tandem Castro-Stephens coupling—6-endo-dig cyclisation of 2-iodo-3-nitrobenzoic acid and arylethynes and ring-closure of methyl 2-alkynyl-3-nitrobenzoates with electrophiles .Tetrahedron. 2006, 62 (20),4829-4837 .

For Pd-catalyzed annulation to give an isocoumarin, see 4,4-Dimethyl-2-pentyne, L10210.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2206859
Harmonized Tariff Code
2916.39
TSCA
Yes

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