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2-Iodobenzoic Acid, methyl ester; 2-Iodobenzoic Acid is a starting material for the preparation of iodosobenzoate, selectivity and environment management. Trivalent iodine compounds perform mild oxidations, oxidative couplings, special iodinations and acetoxylations. Iodobenzoates are used as anti-infective, contraceptive agent and x-ray contrast medium for diagnostic radiology.
Ronald Grigg.; Tossapol Khamnaen.; Shuleewan Rajviroongit.; Visuvanathar Sridharan. Synthesis of N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones via a palladium-catalysed three-component process. Tetrahedron Lett. 2002, 43 (14),2601-2603 .
Esther C.Y. Woon.; Archana Dhami.; Mary F. Mahon.; Michael D. Threadgill. 5-Nitroisocoumarins from tandem Castro-Stephens coupling6-endo-dig cyclisation of 2-iodo-3-nitrobenzoic acid and arylethynes and ring-closure of methyl 2-alkynyl-3-nitrobenzoates with electrophiles .Tetrahedron. 2006, 62 (20),4829-4837 .
For Pd-catalyzed annulation to give an isocoumarin, see 4,4-Dimethyl-2-pentyne, L10210.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.