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20834-61-1 - 2-Bromo-4,6-di-tert-butylphenol, 97% - A13218 - Alfa Aesar

A13218 2-Bromo-4,6-di-tert-butylphenol, 97%

CAS Number
20834-61-1
Synonyms

Size Price ($) Quantity Availability
25g 67.90
100g 230.00
500g 1014.00
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2-Bromo-4,6-di-tert-butylphenol, 97%

MDL
MFCD00051597
EINECS
000-000-0

Chemical Properties

Formula
C14H21BrO
Formula Weight
285.23
Melting point
55-59°

Applications

It is used in pharmaceutical intermediates and as medicine. When 2-Bromo-4,6-di-tert-butylphenol was treated with potassium ferricyanide in benzene 1,4-dihydro-4-bromo-2,4,6,8-tetra-tert-butyl-1-oxodibenzofuran was yielded with a small amount of 2,4,6,8-tetra-tert-butyldibenzofuran.

Notes

Store at room temperature. Incompatible with oxidizing agents.

Literature References

Masashi Tashiro.; Haruo Yoshiya.; Gouki Fukata. Selective preparation. 31. Oxidative coupling of 2-halo-4,6-di-tert-butylphenols with potassium hexacyanoferrate(III) in benzene. J. Org. Chem. 1981, 46 (19),3784-3789 .

Francesco Minisci.; Attilio Citterio.; Elena Vismara.; Francesca Fontana.; Silvia De Bernardinis.; Mariano Correale. Facile and convenient syntheses of quinones from phenols. J. Org. Chem. 1989, 54 (3),728-731 .

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2100150
Harmonized Tariff Code
2908.19
TSCA
No

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