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13331-27-6 - 3-Nitrobenzeneboronic acid, 98% - 3-Nitrophenylboronic acid - 3-Nitrophenylboric acid - A13336 - Alfa Aesar

A13336 3-Nitrobenzeneboronic acid, 98%

CAS Number
13331-27-6
Synonyms
3-Nitrophenylboronic acid
3-Nitrophenylboric acid

Size Price ($) Quantity Availability
1g 16.11
5g 46.71
25g 172.00
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3-Nitrobenzeneboronic acid, 98%

MDL
MFCD00007193

Chemical Properties

Formula
C6H6BNO4
Formula Weight
166.93
Melting point
ca 285° dec.
Sensitivity
Hygroscopic

Literature References

Reagent for derivatization of diols and diamines for GC: Chromatographia, 11, 347 (1978).

/n

Oxidative conversion of arylboronic acids to phenols with potassium monopersulfate in buffered aqueous acetone (in situ dimethyldioxirane) is exemplified for this compound: Tetrahedron Lett., 36, 5117 (1995).

/n

Mild Lewis acid catayst, for example in the selective transesterification of ß-keto esters: Synlett, 415 (2006). See also 3,4,5-Trifluorobenzeneboronic acid, L18519. For reactions of boronic acids, see Appendix 5.

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2938638
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
CY8980000

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