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111-42-2 - Diethanolamine, 99% - Bis(beta-hydroxyethyl)amine - 2,2'-Iminodiethanol - A13389 - Alfa Aesar

A13389 Diethanolamine, 99%

CAS Number
111-42-2
Synonyms
Bis(beta-hydroxyethyl)amine
2,2'-Iminodiethanol

Size Price ($) Quantity Availability
250g 19.36
500g 26.66
2500g 69.63
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Diethanolamine, 99%

MDL
MFCD00002843
EINECS
203-868-0

Chemical Properties

Formula
C4H11NO2
Formula Weight
105.14
Melting point
27-30°
Boiling Point
268-270°
Flash Point
176°(349°F)
Density
1.097
Refractive Index
1.4770
Sensitivity
Hygroscopic
Solubility
Miscible with water.

Applications

Diethanolamine is used in the preparation of morpholine and diethanolamides, which is an active ingredient in cosmetics and shampoos. It acts as a surfactant and a corrosion inhibitor. It is utilized to remove hydrogen sulfide and carbon dioxide from natural gas. Further, it is an intermediate used in the rubber chemicals, as a humectant and a softening agent, and as an emulsifier and dispersing agent in agricultural chemicals. In addition to this, it is used in cutting oils, cleaners, soaps, polishers, and pharmaceuticals.

Notes

Hygroscopic and air sensitive. Incompatible with strong oxidizing agents, strong acids, copper, zinc, carbon dioxide and iron.

Literature References

Boronic acids can be protected as cyclic boronates which are generally high-melting crystalline solids: J. Am. Chem. Soc., 77, 2491 (1955). NMR evidence has been presented indicating that derivatives of this type have a transannular B-N bond: J. Organomet. Chem., 246, 213 (1983):

For use in the modification of a boronic acid cleft in formation of a sodium-saccharide cotransporter, see: J. Org. Chem., 60, 2147 (1995). For use of the butyl cyclic boronate in the formation of a chiral dioxaborolane ligand, see: Org. Synth., 76, 86 (1998). See also Appendix 6.

Hickman, D. A.; Mosner, K.; Ringer, J. W. A continuous diethanolamine dehydrogenation fixed bed catalyst and reactor system. Chem. Eng. J. 2015, 278, 447-453.

Bezgin, F.; Ayaz, N.; Demirelli, K. Synthesis, characterization, and dielectric properties of polymers functionalized with coumarone and diethanolamine. J. Appl. Polym. Sci. 2015, 132 (26), 42164.

Davarpanah, M.; Ahmadpour, A.; Rohani-Bastami, T.; Dabir, H. Synthesis and application of diethanolamine-functionalized polystyrene as a new sorbent for the removal of p-toluenesulfonic acid from aqueous solution. J. Ind. Eng. Chem. 2015, 30, 281-288.

GHS Hazard and Precautionary Statements

Hazard Statements: H318-H315-H373-H302

Causes serious eye damage. Causes skin irritation. May cause damage to organs through prolonged or repeated exposure. Harmful if swallowed.

Precautionary Statements: P260-P280-P264-P305+P351+P338-P310-P362-P301+P312-P321-P332+P313-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3107
Beilstein
605315
Harmonized Tariff Code
2922.12
TSCA
Yes
RTECS
KL2975000

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