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2,5-Dibromothiophene, is mainly used as pharmaceutical intermediate and synthesis intermediate.
JWP Lin.; LP Dudek. Synthesis and properties of poly (2, 5-thienylene). Journal of Polymer Science. 1980, 18,(9), 2869-2873.
. J Nakayama.; N Katano.; Y Shimura. Preparation of Oligo (thio-2, 5-thienylenes). J. Org. Chem. 1996, 61,(21), 7608-7610.
For selective Mg exchange at the 2-position, see: J. Org. Chem., 65, 4618 (2000).
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant