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16001-93-7 - Tetramethyl methylenediphosphonate, 98+% - Methylenediphosphonic acid tetramethyl ester - A13441 - Alfa Aesar

A13441 Tetramethyl methylenediphosphonate, 98+%

CAS Number
16001-93-7
Synonyms
Methylenediphosphonic acid tetramethyl ester

Size Price ($) Quantity Availability
5g 100.63
25g 387.28
100g 1318.40
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Tetramethyl methylenediphosphonate, 98+%

MDL
MFCD00014884

Chemical Properties

Formula
C5H14O6P2
Formula Weight
232.11
Boiling Point
152-154°/2.5mm
Refractive Index
1.4550
Solubility
Miscible with water.

Applications

Tetramethyl methylenediphosphonate is used in the preparation of phosphonate analogue of ribose-1-phosphate.

Notes

Incompatible with strong oxidizing agents.

Literature References

Vinylphosphonate precursor; compare Tetraethyl­ methyl­enediphosphonate, A14532 and Tetraisopropyl­ methyl­enediphosphonate, A13484.

Marquick, A. L.; Montero, J. L.; Lebrun, A.; Barragan-Montero, V. Straightforward synthesis towards mono and bis-phosphonic acid functionalised beta-cyclodextrins. Tetrahedron 2015, 71 (10), 1616-1621.

A Bisceglia, J.; R Orelli, L. Recent Progress in the Horner-Wadsworth-Emmons Reaction. Curr. Org. Chem. 2015, 19 (9), 744-775.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280h-P305+P351+P338

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1874756
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

  • A11967

    Chloromethyl pivalate, 97%
  • A13484

    Tetraisopropyl methylenediphosphonate, 98%
  • A10588

    Tetra-n-butylammonium fluoride, 1M soln. in THF
  • A10645

    Diethyl benzylphosphonate, 99%
  • A11135

    tert-Butylamine, 98%

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