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2969-81-5 - Ethyl 4-bromobutyrate, 98% - 4-Bromobutyric acid ethyl ester - A13470 - Alfa Aesar

A13470 Ethyl 4-bromobutyrate, 98%

CAS Number
2969-81-5
Synonyms
4-Bromobutyric acid ethyl ester

Size Price ($) Quantity Availability
50g 38.32
250g 126.69
1000g 365.40
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Ethyl 4-bromobutyrate, 98%

MDL
MFCD00000259
EINECS
221-005-6

Chemical Properties

Formula
Br(CH2)3CO2CH2CH3
Formula Weight
195.06
Boiling Point
80-82°/10mm
Flash Point
90°(194°F)
Density
1.363
Refractive Index
1.4560
Solubility
Immiscible with water.

Applications

Ethyl 4-bromobutyrate is used as a building block for the preparation of firefly luciferase inhibitor-conjucated peptide derivatives. It finds application in the synthesis of poly(2,6,-dimethyl-1,4-phehylene oxide) and thieno(2,3-b)-azepin-4-ones.

Notes

Incompatible with bases, oxidizing agents and reducing agents.

Literature References

Borzenkov, M.; Mitina, N.; Lobaz, V.; Hevus, O. Synthesis and Properties of Novel Surface Active Monomers Based on Derivatives of 4-Hydroxybutyric Acid and 6-Hydroxyhexanoic Acid. J. Surfactants Deterg. 2015, 18 (1), 133-144.

Ali, S. A.; Muallem, H. A.; Hamouz, O. C. S. O. A.; Estaitie, M. K. Synthesis of a novel zwitterionic bisphosphonate cyclopolymer containing residues of alendronic acid. React. Funct. Polym. 2015, 86, 80-86.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1749700
Harmonized Tariff Code
2915.90
TSCA
No

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