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89-98-5 - 2-Chlorobenzaldehyde, 97% - A13488 - Alfa Aesar

A13488 2-Chlorobenzaldehyde, 97%

CAS Number
89-98-5
Synonyms

Size Price ($) Quantity Availability
10g 15.97
250g 19.36
1000g 73.03
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2-Chlorobenzaldehyde, 97%

MDL
MFCD00003304
EINECS
201-956-3

Chemical Properties

Formula
C7H5ClO
Formula Weight
140.57
Melting point
10-12°
Boiling Point
212°
Flash Point
87°(188°F)
Density
1.249
Refractive Index
1.5675
Sensitivity
Air Sensitive
Solubility
Soluble in water (1.8g/L), alcohol, ether, benzene, and acetone.

Applications

2-Chlorobenzaldehyde has been used in generation of small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and thioureas

Notes

Air Sensitive. Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

M. Rogojerov.; G. Keresztury.; B. Jordanov. Vibrational spectra of partially oriented molecules having two conformers in nematic and isotropic solutions: furfural and 2-chlorobenzaldehyde. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2005, 16, (7), 1661-1670.

Lothar Schafer.; Svein Samdal.; Kenneth Hedberg. An electron-diffraction study of the molecular structure of 2-chlorobenzaldehyde. Journal of Molecular Structure. 1976, 31, (1), 29-37.

For experimental details for the direct conversion to the benzoyl chloride by reaction with chlorine, see: Org. Synth. Coll., 1, 155 (1941).

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H318-H227-H303

Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid. May be harmful if swallowed.

Precautionary Statements: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Other References

Beilstein
385877
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2913.00
TSCA
Yes
RTECS
CU5075000

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