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A13558 2-Iodobenzoyl chloride, 98%

CAS Number
609-67-6
Synonyms

Stock No. Size Price ($) Quantity Availability
A13558-09 10g 55.90
A13558-18 50g 210.00
A13558-30 250g 825.00
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2-Iodobenzoyl chloride, 98%

MDL
MFCD00001040
EINECS
210-196-1

Chemical Properties

Formula
C7H4ClIO
Formula Weight
266.47
Melting point
27-32°
Boiling Point
105-106°/1mm
Flash Point
>110°(230°F)
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

2-Iodobenzoyl chloride has been used in palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones, preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Daniel L. Comins.; Yue-mei Zhang. Anionic Cyclization of Chiral 2,3-Dihydro-4-pyridones:? A Five-Step, Asymmetric Synthesis of Indolizidine 209D. J. Am. Chem. Soc. 1996, 118, (48), 12248-12249.

Gary L. Bolton.; John C. Hodges. Solid-Phase Synthesis of Substituted Benzazepines via Intramolecular Heck Cyclization. J. Comb. Chem. 1999, 1, (2), 130-133.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2042672
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2916.39
TSCA
Yes

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