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592-42-7 - 1,5-Hexadiene, 98% - Biallyl - Diallyl - A13650 - Alfa Aesar

A13650 1,5-Hexadiene, 98%

CAS Number
592-42-7
Synonyms
Biallyl
Diallyl

Size Price ($) Quantity Availability
25g 25.11
100g 66.06
500g 220.00
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1,5-Hexadiene, 98%

MDL
MFCD00008666
EINECS
209-754-7

Chemical Properties

Formula
CH2=CHCH2CH2CH=CH2
Formula Weight
82.15
Melting point
-141°
Boiling Point
58-60°
Flash Point
-27°(-16°F)
Density
0.692
Refractive Index
1.4040
Solubility
Soluble in water(0.17g/L).

Applications

1,5-Hexadiene is used to study the Pd(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes.

Notes

Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Geoffrey W. Coates.; Robert M. Waymouth. Enantioselective cyclopolymerization of 1,5-hexadiene catalyzed by chiral zirconocenes: a novel strategy for the synthesis of optically active polymers with chirality in the main chain. J. Am. Chem. Soc. 1993, 115, (1), 91-98.

Anne Lise Mogstad.; Robert M. Waymouth. Chain transfer to aluminum in the homogeneous cyclopolymerization of 1,5-hexadiene. Macromolecules. 1992, 25, (8), 2282-2284.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H304-H319-H335

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P301+P310-P303+P361+P353-P305+P351+P338-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1731106
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2901.29
TSCA
Yes
RTECS
MM1997800

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