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A13660 Diethyl phenylthiomethylphosphonate, 96%

CAS Number
38066-16-9
Synonyms
Phenylthiomethylphosphonic acid diethyl ester

Stock No. Size Price ($) Quantity Availability
A13660-09 10g 64.70
A13660-18 50g 256.00
A13660-30 250g 1019.00
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Diethyl phenylthiomethylphosphonate, 96%

MDL
MFCD00015130
EINECS
253-770-7

Chemical Properties

Formula
C11H17O3PS
Formula Weight
260.29
Boiling Point
146-148°/0.5mm
Density
1.174
Refractive Index
1.5340
Storage & Sensitivity
Ambient temperatures.
Solubility
Difficult to mix.

Applications

Diethyl phenylthiomethylphosphonate is used to produce Diethylphosphorylmethylphenylsulfoxid, Chemical reagents, pharmaceutical research, pharmaceutical intermediates.

Notes

Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

Literature References

Horner-Wadsworth-Emmons olefination (see Appendix 1) with carbonyl compounds gives enol thioethers, convertible to aldehydes: J. Chem. Soc., 1324 (1963). Compare Diethyl­ methyl­thiomethyl­phosphonate, L00579.

For use in a synthesis of vinylphosphonates, in which the double bond is introduced by sulfoxide elimination, see: Synthesis, 917 (1982):

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1246215
Harmonized Tariff Code
2931.39
TSCA
No

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