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89-62-3 - 4-Methyl-2-nitroaniline, 98+% - 4-Amino-3-nitrotoluene - 2-Nitro-p-toluidine - A13666 - Alfa Aesar

A13666 4-Methyl-2-nitroaniline, 98+%

CAS Number
89-62-3
Synonyms
4-Amino-3-nitrotoluene
2-Nitro-p-toluidine

Size Price ($) Quantity Availability
100g 22.10
500g 53.00
2500g 237.00
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4-Methyl-2-nitroaniline, 98+%

MDL
MFCD00007907
EINECS
201-924-9

Chemical Properties

Formula
C7H8N2O2
Formula Weight
152.15
Melting point
115-118°
Boiling Point
169°/21mm
Flash Point
157°(314°F)
Density
1.31
Solubility
Soluble in water (0.2 g/L at 20°C).

Applications

4-Methyl-2-nitroaniline is used as a red azo dye.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literature References

Michael P. Doyle.; Bernard Siegfried.; Joseph F. DellariaJr. Alkyl nitrite-metal halide deamination reactions. 2. Substitutive deamination of arylamines by alkyl nitrites and copper(II) halides. A direct and remarkably efficient conversion of arylamines to aryl halides. J. Org. Chem. 1977, 42 (14), 2426-2431.

Shoji Kajigaeshi.; Takaaki Kakinami.; Kazuhisa Inoue.; Manabu Kondo.; Hiroko Nakamura.; Masahiro Fujikawa.; Tsuyoshi Okamoto. Halogenation Using Quaternary Ammonium Polyhalides. VI. Bromination of Aromatic Amines by Use of Benzyltrimethylammonium Tribromide. Bulletin of the Chemical Society of Japan. 1988, 61 (2), 597-599.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H373

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260u-P201-P280h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/clothing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
879506
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.43
TSCA
Yes
RTECS
XU8227250

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