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4-Methyl-2-nitroaniline is used as a red azo dye.
Michael P. Doyle.; Bernard Siegfried.; Joseph F. DellariaJr. Alkyl nitrite-metal halide deamination reactions. 2. Substitutive deamination of arylamines by alkyl nitrites and copper(II) halides. A direct and remarkably efficient conversion of arylamines to aryl halides. J. Org. Chem. 1977, 42 (14), 2426-2431.
Shoji Kajigaeshi.; Takaaki Kakinami.; Kazuhisa Inoue.; Manabu Kondo.; Hiroko Nakamura.; Masahiro Fujikawa.; Tsuyoshi Okamoto. Halogenation Using Quaternary Ammonium Polyhalides. VI. Bromination of Aromatic Amines by Use of Benzyltrimethylammonium Tribromide. Bulletin of the Chemical Society of Japan. 1988, 61 (2), 597-599.
Hazard Statements: H301-H311-H331-H373
Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P273-P280h-P309-P310a-P302+P352a
Avoid release to the environment. Wear protective gloves/clothing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor IF ON SKIN: Wash with plenty of water.