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1628-89-3 - 2-Methoxypyridine, 98% - Methyl 2-pyridyl ether - A13675 - Alfa Aesar

A13675 2-Methoxypyridine, 98%

CAS Number
1628-89-3
Synonyms
Methyl 2-pyridyl ether

Size Price ($) Quantity Availability
25g 25.20
500g 293.60
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2-Methoxypyridine, 98%

MDL
MFCD00006262
EINECS
216-623-8

Chemical Properties

Formula
C6H7NO
Formula Weight
109.13
Boiling Point
142-143°
Flash Point
32°(89°F)
Density
1.046
Refractive Index
1.5040

Literature References

Can be metallated at the 3-position with LDA at -70o: J. Org. Chem., 53, 1367 (1988). With the unimetal superbase complex formed from 2 mol of n-BuLi and I mol of 2-(Dimethyl­amino)­ethanol, B23616, in hexane, products are obtained resulting from apparent metallation at the 6-position. A radical mechanism, rather than a true 6-metallation, has been proposed for this reaction: J. Chem. Soc., Perkin 1, 3071 (1997). Analogous results have been reported with 2-chloropyridine: Org. Lett., 2, 803 (2000).

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GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
108189
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
No

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