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A13697 Diethyl iodomethylphosphonate, 98+%

CAS Number
10419-77-9
Synonyms
Diethyl iodomethanephosphonate
Iodomethylphosphonic acid diethyl ester

Stock No. Size Price ($) Quantity Availability
A13697-06 5g 80.40
A13697-14 25g 294.00
A13697-22 100g 976.00
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Diethyl iodomethylphosphonate, 98+%

MDL
MFCD00041386
EINECS
233-895-3

Chemical Properties

Formula
C5H12IO3P
Formula Weight
278.03
Boiling Point
112-114°/1mm
Flash Point
>110°(230°F)
Refractive Index
1.4995
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Immiscible with water.

Applications

Diethyl iodomethylphosphonate is used in the synthesis of H2N-Tyr(tBu)-vinyl sulfone.

Notes

Light sensitive. Incompatible with strong oxidizing agents.

Literature References

Linden, W. A.; Segal, E.; Child, M. A.; Byzia, A.; Drąg, M.; Bogyo, M. Design and Synthesis of Activity-Based Probes and Inhibitors for Bleomycin Hydrolase. Chem. Biol. 2015, 22 (8), 995-1001.

Li, Y.; Huang, H.; Wang, Z.; Yang, F.; Li, D.; Qin, B.; Ren, X. Stereoselective synthesis of C-sulfonylated aziridines from halomethyl phenyl sulfone and N-tert-butanesulfinyl imines. RSC Adv. 2014, 4 (2), 969-973.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1812052
Harmonized Tariff Code
2931.39
TSCA
No

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