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90-59-5 - 3,5-Dibromosalicylaldehyde, 98% - 3,5-Dibromo-2-hydroxybenzaldehyde - A13729 - Alfa Aesar

A13729 3,5-Dibromosalicylaldehyde, 98%

CAS Number
90-59-5
Synonyms
3,5-Dibromo-2-hydroxybenzaldehyde

Size Price ($) Quantity Availability
10g 56.16
50g 179.20
250g 704.00
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3,5-Dibromosalicylaldehyde, 98%

MDL
MFCD00003318
EINECS
202-003-4

Chemical Properties

Formula
C7H4Br2O2
Formula Weight
279.93
Melting point
81-84°
Sensitivity
Air Sensitive
Solubility
Soluble in methanol 25 mg/mL. Insoluble in water.

Applications

3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes. It can be used in the synthesis of Schiff base and can be used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air Sensitive.

Literature References

Yongming Cui; Xiongwei Dong; Yuguang Li; Zuowen Li; Wu Chen. Synthesis, structures and urease inhibition studies of Schiff base metal complexes derived from 3,5-dibromosalicylaldehyde.European Journal of Medicinal Chemistry.2012, 58 323-331.

L Tian; Z Shang; X Zheng; Y Sun; Y Yu; Bochu Qian and Xueli Liu. Synthesis, characterization and biological activity of diphenyltin(IV) complexes of N-(3,5-dibromosalicylidene)-α-amino acid and their diphenyltin dichloride adducts.Applied Organometallic Chemistry.2006, 20 74-80.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,3027
Beilstein
1424739
Harmonized Tariff Code
2913.00
TSCA
No
RTECS
CU5609000

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