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A13791 2-Bromopyrimidine, 98+%

CAS Number
4595-60-2
Synonyms

Stock No. Size Price ($) Quantity Availability
A13791-06 5g 77.50
A13791-14 25g 280.00
A13791-22 100g 1082.00
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2-Bromopyrimidine, 98+%

MDL
MFCD00014601
EINECS
224-993-7

Chemical Properties

Formula
C4H3BrN2
Formula Weight
158.99
Melting point
53-57°
Boiling Point
62-64°/1.5mm
Storage & Sensitivity
Keep Cold.
Solubility
Miscible with water.

Applications

2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.

Notes

Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.

Literature References

Lu, X.; Wang, H.; Gao, R.; Pei, C. One-pot Metal-free Synthesis of Benzyl Alkyl Sulfides. Phosphorus Sulfur Silicon Relat Elem 2015, 190 (1), 45-52.

Huang, R.; Huang, Y.; Lin, X.; Rong, M.; Weng, Z. Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides. Angew. Chem. Int. Ed. 2015, 54 (19), 5736-5739.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
605945
Harmonized Tariff Code
2933.59
TSCA
Yes

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