Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

4595-60-2 - 2-Bromopyrimidine, 98+% - A13791 - Alfa Aesar

A13791 2-Bromopyrimidine, 98+%

CAS Number
4595-60-2
Synonyms

Size Price ($) Quantity Availability
5g 67.60
25g 246.40
100g 856.80
Add to Cart Add to Quote Request View Item

2-Bromopyrimidine, 98+%

MDL
MFCD00014601
EINECS
224-993-7

Chemical Properties

Formula
C4H3BrN2
Formula Weight
158.99
Melting point
53-57°
Boiling Point
62-64°/1.5mm
Solubility
Miscible with water.

Applications

2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.

Notes

Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.

Literature References

Lu, X.; Wang, H.; Gao, R.; Pei, C. One-pot Metal-free Synthesis of Benzyl Alkyl Sulfides. Phosphorus Sulfur Silicon Relat Elem 2015, 190 (1), 45-52.

Huang, R.; Huang, Y.; Lin, X.; Rong, M.; Weng, Z. Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides. Angew. Chem. Int. Ed. 2015, 54 (19), 5736-5739.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
605945
Harmonized Tariff Code
2933.59
TSCA
Yes

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware