Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

589-87-7 - 1-Bromo-4-iodobenzene, 98% - 4-Bromoiodobenzene - A13859 - Alfa Aesar

A13859 1-Bromo-4-iodobenzene, 98%

CAS Number
589-87-7
Synonyms
4-Bromoiodobenzene

Size Price ($) Quantity Availability
10g 37.90
50g 143.04
250g 457.60
Add to Cart Add to Quote Request View Item

1-Bromo-4-iodobenzene, 98%

MDL
MFCD00001051
EINECS
209-662-7

Chemical Properties

Formula
C6H4BrI
Formula Weight
282.91
Melting point
89-93°
Boiling Point
252°
Sensitivity
Light Sensitive
Solubility
Insoluble in water.

Applications

It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).

Notes

Light sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent, light.

Literature References

Shenlin Huang; James M. Tour. Rapid bi-directional synthesis of oligo(1, 4-phenylene ethynylene)s. Tetrahedron Letters. 1999, 40 (17), 3447-3450.

Harry A.J. Oonk; Peter R. van der Linde; Jan Huinink; Jacobus G. Blok. Representation and assessment of vapour pressure data; a novel approach applied to crystalline 1-bromo-4-chlorobenzene, 1-chloro-4-iodobenzene, and 1-bromo-4-iodobenzene. J. Chem. Thermodyn. 1998, 30 (7), 897-907.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1904545
Harmonized Tariff Code
2903.99
TSCA
Yes

Recommended

  • A10459

    Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine
  • A10517

    1,4-Dibromobenzene, 98%
  • A13529

    p-Toluenesulfonyl hydrazide, 98%
  • L14002

    Silica gel 60, 0.060-0.2mm (70-230 mesh)
  • 10548

    Tetrakis(triphenylphosphine)palladium(0), 99.8% (metals basis), Pd 9% min

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware