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A13864 Tritylamine, 98%

CAS Number
5824-40-8
Synonyms
Triphenylmethylamine

Stock No. Size Price ($) Quantity Availability
A13864-03 1g 21.60
A13864-06 5g 74.40
A13864-14 25g 241.00
A13864-22 100g 941.00
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Tritylamine, 98%

MDL
MFCD00008047

Chemical Properties

Formula
(C6H5)3CNH2
Formula Weight
259.35
Melting point
100-104°
Boiling Point
223°/14mm
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in chloroform, methanol. Insoluble in water.

Applications

Triphenylmethylamine was used to prepare diamondoid porous organic salt.1 It was also used in preparation of N-tritylated β-amino alcohols, useful building blocks in organic synthesis. It is used in the preparation of trityl- cysteine analogs as inhibitors of human mitotic kinesin.

Notes

Air sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent.

Literature References

Atsushi Yamamoto; Tetsuya Hasegawa; Tomoya Hamada; Tomofumi Hirukawa; Ichiro Hisaki; Mikiji Miyata; Norimitsu Tohnai. Role-allocated combination of two types of hydrogen bonds towards constructing a breathing diamondoid porous organic salt. Chemistry: A European Journal. 2013, 19 (9), 3006-3016.

Sushil K. Sharma; Michael F. Songster; Tracey L. Colpitts; Peter Hegyes; George Barany; Francis J. Castellino. Reductive amination with tritylamine as an ammonia equivalent: efficient preparation of the 5-(4-(9-fluorenylmethyloxycarbonyl)aminomethyl-3,5-dimethoxyphenoxy)valeric acid (PAL) handle for peptide synthesis. J. Org. Chem., 1993, 58 (18), 4993-4996.

Protected form of ammonia: the trityl group is removable by strong acid. For use in the synthesis of 1-aminoalkanephosphonic esters or acids, see: Synthesis, 370 (1988):

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2113674
Harmonized Tariff Code
2921.45
TSCA
No

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