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943-89-5 - trans-4-Methoxycinnamic acid, 98% - A13870 - Alfa Aesar

A13870 trans-4-Methoxycinnamic acid, 98%

CAS Number
943-89-5
Synonyms

Size Price ($) Quantity Availability
10g 14.40
50g 57.99
250g 176.00
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trans-4-Methoxycinnamic acid, 98%

MDL
MFCD00004398
EINECS
213-405-4

Chemical Properties

Formula
C10H10O3
Formula Weight
178.19
Melting point
171-175°
Solubility
Soluble in ethanol, ethyl acetate and other organic solvents.

Applications

Esters derived from trans-4-methoxycinnamic acid are effective absorbers of UV radiation. The starting material was trans-4-methoxycinnamic acid and 3,5dimethoxybenzoic acid methyl ester in isolated avenanthramide alkaloids synthsis. trans-4-Methoxycinnamic acid was converted into its acid chloride (yield 98%) with thionyl chloride. Employed in organic synthesis of pharmaceutical intermediates, synthetic anti-adrenergic drugs esmolol, cosmetics ultraviolet absorption.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literature References

Anton Blaakmeer,; Dick van der Wal,; André Stork,; Teris A. van Beek,; Aede de Groot,; Joop J. A. van Loon. Structure-Activity Relationship of Isolated Avenanthramide Alkaloids and Synthesized Related Compounds as Oviposition Deterrents for Pieris brassicae . J. Nat. Prod., . 1994, 57 (8), 1145-1151.

Ryan G. Stabile,; Andrew P. Dicks. Two-Step Semi-Microscale Preparation of a Cinnamate Ester Sunscreen Analog. J. Chem. Educ. 2004, 81 (10), 1488.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
510468
Harmonized Tariff Code
2918.99
TSCA
Yes
RTECS
UD3391300

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