Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

590-17-0 - Bromoacetonitrile, 96% - A13933 - Alfa Aesar

A13933 Bromoacetonitrile, 96%

CAS Number
590-17-0
Synonyms

Size Price ($) Quantity Availability
10g 32.96
50g 98.16
250g 369.44
Add to Cart Add to Quote Request View Item

Bromoacetonitrile, 96%

MDL
MFCD00001884
EINECS
209-672-1

Chemical Properties

Formula
BrCH2CN
Formula Weight
119.95
Boiling Point
150°
Flash Point
81°(178°F)
Density
1.722
Refractive Index
1.4800
Solubility
Insoluble in water.

Applications

Bromoacetonitrile was used in the synthesis of 1-cyanomethyl-1,1-dimethylhydrazinium bromide. It is used as an alkalyting agent for the nitrogen phosphorus detector.

Notes

Store in a cool, dry, well-ventilated area. Incompatible with oxidizing agent.

Literature References

Carles Miró Sabaté; Henri Delalu; Erwann Jeanneau. Synthesis, characterization, and energetic properties of salts of the 1-cyanomethyl-1,1-dimethylhydrazinium cation. Chemistry An Asian Journal. 2012, 7 (5), 1085-1095 .

Ho-Sang. Shin; Seungki. Kim; Seung-Woon. Myung; Jong-Sei. Park. Iodoacetonitrile and Bromoacetonitrile as Alkylating Reagents for the Nitrogen-Phosphorus Detector. Anal. Chem. 1995, 67 (11), 1853-1859.

Phenols can be protected (K2CO3, acetone) as their cyanomethyl ethers which can be cleaved by hydrogenation of the nitrile: Tetrahedron Lett., 34, 7567 (1993).

The Reformatsky-type reaction with cyclohexanone is more successful in the presence of a Zn/Ag couple than with the conventional Zn-Cu couple: Synth. Commun., 19, 2355 (1989). Good yields of ß-hydroxy nitriles have also been achieved from aldehydes and ketones using Zn and TMS chloride: Tetrahedron Lett., 31, 2205 (1990). The condensation with aldehydes can also be mediated by active Ni: Tetrahedron Lett., 26, 155 (1985). The reaction with aldehydes in the presence of Zn and tri-n-butylphosphine gives ɑß-unsaturated nitriles directly: Synth. Commun., 20, 3277 (1990).

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H331-H315-H319-H335-H227

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P311-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
956569
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
AL7970000

Recommended

  • A10356

    3,4-Dimethoxycinnamic acid, predominantly trans, 99%
  • A10482

    3-Hydroxy-4-methoxycinnamic acid, predominantly trans, 98+%
  • A10612

    Dichloroacetonitrile, 98+%
  • A11032

    Chloroiodomethane, 98%, stab. with copper
  • A11450

    Potassium ethyl xanthate, 98%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware