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It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals.
Ken Tanaka; Tomoko Hori;Takuya Osaka; Keiichi Noguchi and Masao Hirano. Rhodium-Catalyzed Reactions of Dithiols and 1,4-Bis(bromomethyl)benzenes Leading To Enantioenriched Dithiaparacyclophanes. Org. Lett. 2007, 9 (23), 4881-4884.
Keiiti Sisido; Nobuo Kusano; Ryôzi Noyori; Yôko Nozaki; Masatosi Simosaka and Hitosi Nozaki. Polycondensation of xylylene dibromides by transition metals in water suspension. Journal of Polymer Science Part A: General Papers. 1963, 1 (6), 2101-2107.
Reductive coupling has been used in a relatively high-yielding route to [2,2]-p-cyclophanes: Chem. Lett., 13 (1989); J. Chem. Soc., Perkin 1, 2029 (1991). Used in template-directed synthesis of rigid cyclophane receptor: Synlett, 462 (1991). For use in rotaxane synthesis, see: Synlett, 8975 (1992).
Hazard Statements: H314-H318
Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant