Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

591-17-3 - 3-Bromotoluene, 98% - 3-Methylbromobenzene - A13990 - Alfa Aesar

A13990 3-Bromotoluene, 98%

CAS Number
591-17-3
Synonyms
3-Methylbromobenzene

Size Price ($) Quantity Availability
25g 44.46
100g 125.75
500g 498.60
Add to Cart Add to Quote Request View Item

3-Bromotoluene, 98%

MDL
MFCD00000085
EINECS
209-702-3

Chemical Properties

Formula
C7H7Br
Formula Weight
171.04
Melting point
-40°
Boiling Point
183-184°
Flash Point
75°(167°F)
Density
1.410
Refractive Index
1.5520
Solubility
Not miscible in water. Soluble in alcohols, ether and benzene.

Applications

3-Bromotoluene was used in the precise determination of bromine isotope ratio in organic compounds by MC-ICPMS ( Multicollector-Inductively Coupled Plasma Mass Spectrometer). It undergoes palladium-catalyzed cyanation reaction in the presence of K4[Fe(CN)6] as the cyanide surrogate. It also undergoes palladium-catalyzed reaction with alkynyltriarylborates to yield trisubstituted alkenylboranes.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Pui Yee Yeung; Chun Pui Tsang; Fuk Yee Kwong. Efficient cyanation of aryl bromides with K4[Fe(CN)6] catalyzed by a palladium-indolylphosphine complex. Tetrahedron Letters. 2011, 52,(52), 7038-7041.

 

Faina Gelman; Ludwik Halicz. High precision determination of bromine isotope ratio by GC-MC-ICPMS. International Journal of Mass Spectrometry. 2010, 289,(2-3), 167-169.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335-H227

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P210-P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,1439
Beilstein
1903633
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
XS7965400

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware