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A14012 3-Picoline, 99%

CAS Number
108-99-6
Synonyms
3-Methylpyridine

Stock No. Size Price ($) Quantity Availability
A14012-AE 100ml 21.90
A14012-0F 2500ml 114.00
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3-Picoline, 99%

MDL
MFCD00006402
EINECS
203-636-9

Chemical Properties

Formula
C6H7N
Formula Weight
93.13
Melting point
-18°
Boiling Point
143-144°
Flash Point
36°(96°F)
Density
0.955
Refractive Index
1.5055
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Miscible with water, alcohol, ether, acetone, carbon tetrachloride.

Applications

3-Picoline is used as a precursor in pharmaceuticals and agricultural industries. It acts as a precursor to 3-cyanopyridine, niacin, vitamin-B. It is an antidote for organophosphate poisoning.

Notes

Hygroscopic. Incompatible with acids, acid chlorides and chloroformates.

Literature References

Du, Q.; Wang, T.; Wang, Z.; Jiang, X.; Wang, L. Rapid Determination of Glutamine in Human Plasma by High-Performance Liquid Chromatographic-Tandem Mass Spectrometry and Its Application in Pharmacokinetic Studies. J. Chromatogr. Sci. 2015, 53 (1), 79-84.

Cheng, C.; Hartwig, J. F. Iridium-Catalyzed Silylation of Aryl C-H Bonds. J. Am. Chem. Soc. 2015, 137 (2), 592-595.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H311-H314-H332

Flammable liquid and vapour. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Harmful if inhaled.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7401
Beilstein
1366
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
TJ5000000

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