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A14021 Tri(p-tolyl)phosphine, 98%

CAS Number
1038-95-5
Synonyms
Tris(4-methylphenyl)phosphine
Tris(p-tolyl)phosphine

Stock No. Size Price ($) Quantity Availability
A14021-03 1g 15.50
A14021-06 5g 50.30
A14021-14 25g 211.00
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Tri(p-tolyl)phosphine, 98%

MDL
MFCD00008542
EINECS
213-863-5

Chemical Properties

Formula
C21H21P
Formula Weight
304.37
Melting point
144-146°
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Tri(p-tolyl)phosphine is used as pharmaceutical intermediate.

Notes

Air sensitive. Incompatible with oxidizing agents.

Literature References

Sotiris Zartilasa; Sotiris K.Hadjikakoua; Nick Hadjiliadisa; Nikolaos Kourkoumelisa; Loukas Kyrosa; Maciej Kubickib; Martin Barilc; Ian S.Butlerc; Spyros Karkabounasd; Jan Balzarinie. Tetrameric 1:1 and monomeric 1:3 complexes of silver(I) halides with tri(p-tolyl)-phosphine: A structural and biological study. Inorganica Chimica Acta. 2009, 362,(3), 1003-1010.

 

E.L.Muetterties; C.W.Alegranti. Solution structure and kinetic study of metal-phosphine and-phosphite complexes. I. Silver (I) system. J. Am. Chem. Soc. 1972, 94,(18), 6386-6391.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
651045
Harmonized Tariff Code
2931.39
TSCA
Yes
RTECS
SZ3880000

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