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108-37-2 - 1-Bromo-3-chlorobenzene, 99% - 3-Bromochlorobenzene - A14026 - Alfa Aesar

A14026 1-Bromo-3-chlorobenzene, 99%

CAS Number
108-37-2
Synonyms
3-Bromochlorobenzene

Size Price ($) Quantity Availability
100g 66.23
500g 207.20
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1-Bromo-3-chlorobenzene, 99%

MDL
MFCD00000568
EINECS
203-575-8

Chemical Properties

Formula
C6H4BrCl
Formula Weight
191.46
Melting point
-22°
Boiling Point
195-196°
Flash Point
80°(176°F)
Density
1.630
Refractive Index
1.5770
Solubility
Not miscible in water.

Applications

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literature References

Lei Shi; Yuanyuan Chu; Paul Knochel; Herbert Mayr. Kinetics of bromine-magnesium exchange reactions in substituted bromobenzenes. Journal of Organic Chemistry. 2009, 74,(7), 2760-2764.

 

M.Mahmoodi-Darian; S.X.Tian; S.Denifl; S.Matejcik; T.D.Mark; P.Scheier. Temperature dependence of dissociative electron attachment to 1-bromo-2-chlorobenzene and 1-bromo-3-chlorobenzene. International Journal of Mass Spectrometry. 2010, 293,(1-3), 51-55.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Beilstein
1446353
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CY9005000

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