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A14053 1-Bromo-3,5-difluorobenzene, 98%

CAS Number
461-96-1
Synonyms
3,5-Difluorobromobenzene

Stock No. Size Price ($) Quantity Availability
A14053-06 5g 29.00
A14053-14 25g 96.00
A14053-22 100g 324.00
A14053-30 250g 738.00
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1-Bromo-3,5-difluorobenzene, 98%

MDL
MFCD00010305
EINECS
416-710-2

Chemical Properties

Formula
C6H3BrF2
Formula Weight
192.99
Melting point
-27°
Boiling Point
140-141°
Flash Point
44°(111°F)
Density
1.676
Refractive Index
1.4990
Storage & Sensitivity
Ambient temperatures.

Literature References

Lithiation with lithium 2,2,6,6-tetramethylpiperidide (LTMP) at -75o occurs at the 4-position, affording 4-bromo-2,6-difluorobenzoic acid in 84% yield after carboxylation: Tetrahedron Lett., 37, 6551 (1996).

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GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H317-H319-H373

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P260-P264b-P270-P272-P280-P301+P312-P303+P361+P353-P305+P351+P338-P314-P330-P333+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1931520
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2903.99
TSCA
No

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