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100-69-6 - 2-Vinylpyridine, 97%, stab. with 0.1% 4-tert-butylcatechol - A14056 - Alfa Aesar

A14056 2-Vinylpyridine, 97%, stab. with 0.1% 4-tert-butylcatechol

CAS Number
100-69-6
Synonyms

Size Price ($) Quantity Availability
100ml 24.82
500ml 83.84
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2-Vinylpyridine, 97%, stab. with 0.1% 4-tert-butylcatechol

MDL
MFCD00006355
EINECS
202-879-8

Chemical Properties

Formula
C7H7N
Formula Weight
105.14
Melting point
-50°
Boiling Point
159°
Flash Point
47°(117°F)
Density
0.974
Refractive Index
1.5500
Solubility
Soluble in water (27g/L). Slightly soluble in chloroform and methanol.

Applications

2-Vinylpyridine is a pyridine derivative used in the preparation of poly(2-vinylpyridine) via radical polymerization. 2-Vinylpyridine is used to improve effectiveness of protective polymer coatings on metals. It is a reagent for pyridylethylation for new protection method for active hydrogen compounds.. It is also used as basic materials for one of largest-selling plastic, manufacturing pharmaceuticals and bio-compounds.

Notes

Keep container tightly sealed. Store away from oxidizing agent.

Literature References

Hanno Hückstädt; Astrid Göpfert; andVolker Abetz. Synthesis and morphology of ABC heteroarm star terpolymers of polystyrene, polybutadiene and poly(2-vinylpyridine). Macromolecular Chemistry and Physics. 2000, 201(3), 296-307.

Lyudmila M. Bronstein; Stas N. Sidorov; Pyotr M. Valetsky; Jürgen Hartmann; Helmut Cölfen; and Markus Antonietti. Induced Micellization by Interaction of Poly(2-vinylpyridine)-block-poly(ethylene oxide) with Metal Compounds. Micelle Characteristics and Metal Nanoparticle Formation. Langmuir. 1999, 15(19), 6256-6262.

Reacts with chlorocarbenes, generated photochemically, thermally or with ultrasound to give indolizines in one step: J. Chem. Soc., Chem. Commun., 509 (1994); e.g., chlorophenylcarbene, generated thermally from 3-chloro-3-phenyldiazirine:

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H311-H330-H314-H318-H226

Toxic if swallowed. Toxic in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour.

Precautionary Statements: P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
104505
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
UU1040000

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