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A14089 Triphenylphosphine, flake, 99%

CAS Number
603-35-0
Synonyms
TPP

Stock No. Size Price ($) Quantity Availability
A14089-30 250g 43.40
A14089-0B 1000g 130.00
A14089-0I 5000g 506.00
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Triphenylphosphine, flake, 99%

MDL
MFCD00003043
EINECS
210-036-0

Chemical Properties

Formula
(C6H5)3P
Formula Weight
262.29
Melting point
79-81°
Boiling Point
360°
Flash Point
181°(358°F)
Density
1.200
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water. Soluble in benzene, acetone, carbon tetrachloride, ether, and glacial acetic acidSoluble in ether, benzene, carbon tetrachloride, glacial acetic acid, acetone, chloroform and alcohol. Insoluble in water.

Applications

In the synthesis of organic compounds, phosphonium salts and other phosphorus compounds, and as a polymerization initiatorTriphenylphosphine is used in the synthesis of organic compounds due to its nucleophilicity and its reducing character. It is involved in the synthesis of biaryl compounds, phosphonium salts and other phosphorus compounds. As a reducing agent, it is used to prepare aromatic amines from the corresponding aromatic N-oxides. The anionic phosphine is usually isolated as the trisodium salt, which reacts with rhodium to form a complex that finds use in industrial hydroformylation reactions. It is also used to prepare Wilkinson's catalyst, RhCl(PPh3)3 useful to catalyze the hydrogenation of alkenes and tetrakis(triphenylphosphine)palladium(0) that is widely used to catalyse C-C coupling reactions in organic synthesis.

Notes

Incompatible with oxidizing agents and acids.

Literature References

Lenstra, D. C.; Rutjes, F. P.; Mecinovic, J. Triphenylphosphine-catalysed amide bond formation between carboxylic acids and amines. Chem. Commun. 2014, 50 (43), 5763-5766.

Maleki, A.; Rahimi, R.; Maleki, S.; Hamidi, N. Synthesis and characterization of magnetic bromochromate hybrid nanomaterials with triphenylphosphine surface-modified iron oxide nanoparticles and their catalytic application in multicomponent reactions. RSC Adv. 2014, 4 (56), 29765-29771.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H317-H373

Harmful if swallowed. May cause an allergic skin reaction. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P272-P280g-P301+P312-P302+P352-P314-P330-P333+P313-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. Get medical advice/attention if you feel unwell. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,9743
Beilstein
610776
Harmonized Tariff Code
2931.39
TSCA
Yes
RTECS
SZ3500000

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