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A14102 2-(Chloromethyl)quinoline hydrochloride, 97%

CAS Number
3747-74-8
Synonyms
alpha-Chloroquinaldine hydrochloride

Stock No. Size Price ($) Quantity Availability
A14102-03 1g 26.90
A14102-06 5g 89.40
A14102-14 25g 358.00
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2-(Chloromethyl)quinoline hydrochloride, 97%

MDL
MFCD00012734
EINECS
223-145-3

Chemical Properties

Formula
C10H8ClN•HCl
Formula Weight
214.10
Melting point
184-190°
Storage & Sensitivity
Ambient temperatures.

Literature References

As with 2-(Chloromethyl)­pyridine hydrochloride, A10226, lithiation of the free base can be effected at the methylene group. Quinolylaziridines are formed on subsequent reaction with imines: J. Org. Chem., 60, 2279 (1995).

/n

The free base has been used in the protection of OH groups as 2-quinolinylmethyl (Qm) ethers which can be cleaved by aerial oxidation in the presence of Cu(II): J. Org. Chem., 55, 5344 (1990), or by photolysis: Tetrahedron, 48, 10563 (1992). The protection of thiols has also been reported, as the Qm thioethers, which can be cleaved with Fe(III) or Cu(II): Chem. Lett., 803 (1993).

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GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H317-H319-H335

Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P272-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P333+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3565832
Harmonized Tariff Code
2933.49
TSCA
No

Recommended

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