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3747-74-8 - 2-(Chloromethyl)quinoline hydrochloride, 97% - alpha-Chloroquinaldine hydrochloride - A14102 - Alfa Aesar

A14102 2-(Chloromethyl)quinoline hydrochloride, 97%

CAS Number
3747-74-8
Synonyms
alpha-Chloroquinaldine hydrochloride

Size Price ($) Quantity Availability
1g 26.70
5g 78.80
25g 356.40
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2-(Chloromethyl)quinoline hydrochloride, 97%

MDL
MFCD00012734
EINECS
223-145-3

Chemical Properties

Formula
C10H8ClN•HCl
Formula Weight
214.10
Melting point
184-190°

Literature References

As with 2-(Chloromethyl)­pyridine hydrochloride, A10226, lithiation of the free base can be effected at the methylene group. Quinolylaziridines are formed on subsequent reaction with imines: J. Org. Chem., 60, 2279 (1995).

/n

The free base has been used in the protection of OH groups as 2-quinolinylmethyl (Qm) ethers which can be cleaved by aerial oxidation in the presence of Cu(II): J. Org. Chem., 55, 5344 (1990), or by photolysis: Tetrahedron, 48, 10563 (1992). The protection of thiols has also been reported, as the Qm thioethers, which can be cleaved with Fe(III) or Cu(II): Chem. Lett., 803 (1993).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H318-H315-H317-H335

Causes serious eye damage. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P310-P362-P312-P363-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3565832
Harmonized Tariff Code
2933.49
TSCA
No

Recommended

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  • B22275

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