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95-56-7 - 2-Bromophenol, 98% - A14112 - Alfa Aesar

A14112 2-Bromophenol, 98%

CAS Number
95-56-7
Synonyms

Size Price ($) Quantity Availability
25g 91.05
100g 290.15
500g 1110.40
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2-Bromophenol, 98%

MDL
MFCD00002146
EINECS
202-432-7

Chemical Properties

Formula
C6H5BrO
Formula Weight
173.01
Melting point
Boiling Point
194-195°
Flash Point
89°(192°F)
Density
1.636
Refractive Index
1.5890
Sensitivity
Light Sensitive
Solubility
Soluble in chloroform and ether. Slightly soluble in water.

Applications

2-Bromophenol used as a disinfection byproduct found in chlorinated pool water. Used in the preparation of anti-benzofurobenzofuran diimides. It was also used to study the photodegradation of 2-bromophenol using UV-Vis spectroscopy and HPLC.

Notes

Light sensitive. Store in dark. Store in cool, dry place in tightly closed containers.

Literature References

Sabin-Lucian Suraru et. al. Diindole-annulated naphthalene diimides: synthesis and optical and electronic properties of syn- and anti-isomers. Journal of Organic Chemistry. 2014, 79 (1), 128-139.

Jayaraman A; Mas S; Tauler R, et al. Study of the photodegradation of 2-bromophenol under UV and sunlight by spectroscopic, chromatographic and chemometric techniques. J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 2012, 910 (1), 138-48.

Reacts with n-BuLi to give a dilithio derivative, which reacts with electrophiles at carbon in a useful synthesis of ortho-substituted phenols: J. Org. Chem., 49, 5267 (1984).

GHS Hazard and Precautionary Statements

Hazard Statements: H400-H302-H312-H315-H319-H335-H227

Very toxic to aquatic life. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Precautionary Statements: P261-P273-P280h-P305+P351+P338

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Other References

Merck
14,1428
Beilstein
1905115
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2908.19
TSCA
Yes
RTECS
SJ7875000

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