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A14112 2-Bromophenol, 98%

CAS Number
95-56-7
Synonyms

Stock No. Size Price ($) Quantity Availability
A14112-14 25g 95.70
A14112-22 100g 338.00
A14112-36 500g 1473.00
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2-Bromophenol, 98%

MDL
MFCD00002146
EINECS
202-432-7

Chemical Properties

Formula
C6H5BrO
Formula Weight
173.01
Melting point
Boiling Point
194-195°
Flash Point
92°(192°F)
Density
1.636
Refractive Index
1.5890
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Soluble in chloroform and ether. Slightly soluble in water.

Applications

2-Bromophenol used as a disinfection byproduct found in chlorinated pool water. Used in the preparation of anti-benzofurobenzofuran diimides. It was also used to study the photodegradation of 2-bromophenol using UV-Vis spectroscopy and HPLC.

Notes

Light sensitive. Store in dark. Store in cool, dry place in tightly closed containers.

Literature References

Sabin-Lucian Suraru et. al. Diindole-annulated naphthalene diimides: synthesis and optical and electronic properties of syn- and anti-isomers. Journal of Organic Chemistry. 2014, 79 (1), 128-139.

Jayaraman A; Mas S; Tauler R, et al. Study of the photodegradation of 2-bromophenol under UV and sunlight by spectroscopic, chromatographic and chemometric techniques. J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 2012, 910 (1), 138-48.

Reacts with n-BuLi to give a dilithio derivative, which reacts with electrophiles at carbon in a useful synthesis of ortho-substituted phenols: J. Org. Chem., 49, 5267 (1984).

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1428
Beilstein
1905115
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2908.19
TSCA
Yes
RTECS
SJ7875000

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