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623-04-1 - 4-Aminobenzyl alcohol, 98% - 4-(Hydroxymethyl)aniline - A14130 - Alfa Aesar

A14130 4-Aminobenzyl alcohol, 98%

CAS Number
623-04-1
Synonyms
4-(Hydroxymethyl)aniline

Size Price ($) Quantity Availability
5g 78.12
25g 312.30
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4-Aminobenzyl alcohol, 98%

MDL
MFCD00014782
EINECS
210-767-5

Chemical Properties

Formula
C7H9NO
Formula Weight
123.16
Melting point
59-63°
Sensitivity
Air & Light Sensitive
Solubility
Soluble in alcohol, ether and benzene. Partially soluble in water.

Applications

4-Aminobenzyl alcohol is used in the synthesis of 4-{N-[1-(4,4-dimethyl-2,6-dioxocyclohexylidene)-3-methylbutylamino}benzyl ester. It is also used as an intermediate in organic synthesis and pharmaceutical products.

Notes

Air and light sensitive. Incompatible with strong oxidizing agents and strong acids. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place.

Literature References

Buffa, F.; Hu, H.; Resasco, D. E. Side-Wall Functionalization of Single-Walled Carbon Nanotubes with 4-Hydroxymethylaniline Followed by Polymerization of ε-Caprolactone. Macromolecules 2005, 38 (20), 8258-8263.

Takahashi, H.; Kashiwa, N.; Kobayashi, H.; Hashimoto, Y.; Nagasawa, K. Nucleophilic substitution on 4-hydroxymethylanilines under ‘neutral’ conditions via aza quinone methide intermediate. Tetrahedron Lett. 2002, 43 (33), 5751-5753.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2078680
Harmonized Tariff Code
2922.19
TSCA
No

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