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372-19-0 - 3-Fluoroaniline, 98+% - A14228 - Alfa Aesar

A14228 3-Fluoroaniline, 98+%

CAS Number
372-19-0
Synonyms

Size Price ($) Quantity Availability
25g 40.41
100g 127.20
500g 493.60
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3-Fluoroaniline, 98+%

MDL
MFCD00007758
EINECS
206-747-0

Chemical Properties

Formula
C6H6FN
Formula Weight
111.12
Boiling Point
186-187°
Flash Point
77°(170°F)
Density
1.156
Refractive Index
1.5440
Solubility
Miscible with ethanol and ethyl ether. Slightly miscible with chloroform and water.

Applications

3-Fluoroaniline is used in the preparation of acetic acid-(3-fluoro-anilide by reacting with acetic acid anhydride. Further, it serves as a reagent in the preparation of radamide analogs as Grp94 inhibitors, which has potential to be antitumor agents.

Notes

Incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents.

Literature References

Zhou, Y.; Yuan, Y.; You, L.; Anslyn, E. V. Dynamic Aminal-Based TPA Ligands. Chem. Eur. J. 2015, 21 (22), 8207-8213.

Yashkina, E. A.; Yashkin, S. N.; Svetlov, D. A.; Gorshkov, V. V. Themodynamics of adsorption and patterns of the gas-chromatographic retention of cyclic amines on surfaces of graphitized thermal carbon black. Russ. J. Phys. Chem. A 2015, 89 (9), 1672-1682.

GHS Hazard and Precautionary Statements

Hazard Statements: H331-H302-H312-H315-H319-H373-H227

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Combustible liquid.

Precautionary Statements: P210-P260-P261-P280-P305+P351+P338-P304+P340-P311-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1305471
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2921.42
TSCA
No
RTECS
BY1400000

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