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383-62-0 - Ethyl chlorodifluoroacetate, 98% - Chlorodifluoroacetic acid ethyl ester - A14232 - Alfa Aesar

A14232 Ethyl chlorodifluoroacetate, 98%

CAS Number
383-62-0
Synonyms
Chlorodifluoroacetic acid ethyl ester

Size Price ($) Quantity Availability
25g 75.78
100g 209.60
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Ethyl chlorodifluoroacetate, 98%

MDL
MFCD00013662
EINECS
206-850-0

Chemical Properties

Formula
ClF2CCO2CH2CH3
Formula Weight
158.53
Boiling Point
96-97°
Flash Point
18°(64°F)
Density
1.252
Refractive Index
1.3580
Sensitivity
Moisture Sensitive

Literature References

For conversion to difluoromalonaldehyde derivatives, see: J. Chem. Soc., Chem. Commun., 540 (1992). These may be used in the synthesis of ɑ, ɑ -difluoro functionalized esters and amides.

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Wittig reactions with phosphorus ylides give enol ethers, which are useful precursors of various fluorinated derivatives: J. Org. Chem., 57, 3807 (1992); Org. Synth., 75, 153 (1997). See Ethyl­ trifluoroacetate, A11520, for reaction scheme.

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GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1761413
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2915.90
TSCA
Yes

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