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1-Phenyl-1H-pyrazole is used in the preparation of 4,5-diphenylpyrazolo[1,5-a]quinoline, 1-(1,2,3,4-tetraphenylnaphthalen-5-yl)pyrazole and 1-(1,2,3,4,5,6,7,8-octaphenylanthracen-9-yl)pyrazole. It acts as a cyclometallated ligand in the preparation of new heteroleptic iridium(III) complexes.
Nobuyoshi Umeda; Koji Hirano; Tetsuya Satoh; Naoto Shibata; Hirofumi Sato; Masahiro Miura. Rhodium-catalyzed oxidative 1:1, 1:2, and 1:4 coupling reactions of phenylazoles with internal alkynes through the regioselective cleavages of multiple C-H bonds. Journal of Organic Chemistry.2011, 76 (1), 13-24.
Indira Fabre; Niklas von Wolff; Gaëtan Le Duc; Emmanuel Ferrer Flegeau; Christian Bruneau; Pierre H Dixneuf; Anny Jutand. Autocatalytic intermolecular versus intramolecular deprotonation in C-H bond activation of functionalized arenes by ruthenium(II) or palladium(II) complexes. Chemistry: A European Journal.2013, 19 (23), 7595-7604.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.