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A14281 3-Nitrophthalic acid, 95%

CAS Number
603-11-2
Synonyms

Stock No. Size Price ($) Quantity Availability
A14281-22 100g 49.50
A14281-30 250g 82.80
A14281-36 500g 164.00
A14281-0E 2500g 756.00
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3-Nitrophthalic acid, 95%

MDL
MFCD00007138
EINECS
210-030-8

Chemical Properties

Formula
C8H5NO6
Formula Weight
211.13
Melting point
ca 214° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Solubility in methanol is almost transparent. Soluble in 5% water.

Applications

3-Nitrophthalic acid can be used as starting reagent in the synthesis of modified 2-iodoxybenzoic acid derivatives. It may be used in the synthesis of brucinium 2-carboxy-6-nitrophthalate dihydrate (systematic name: 2,3-dimethoxy-10-oxostrychnidinium 2-carboxy-6-nitrophthalate dihydrate), via heating with brucine. Clyatt E

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Tohma H and Kita Y. Hypervalent iodine reagents for the oxidation of alcohols and their application to complex molecule synthesis.Adv. Synth. Catal.,2004,346(2-3), 111-124.

Smith G, et al. Brucinium 2-carboxy-6-nitrophthalate dihydrate: the 1: 1 proton-transfer compound of brucine with 3-nitrophthalic acid.Acta Crystallogr. Sect. E Struct. Rep. Online.,2005,61(7), 2008-11.

Drakeford, et. al. Fate of isoxaben in a containerized plant rhizosphere system.Chemosphere.,2003,50(9), 1243-1247.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335-H500

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May form combustible dust concentrations in air

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
2054269
Harmonized Tariff Code
2917.39
TSCA
Yes

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