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107-05-1 - Allyl chloride, 98%, stab. with propylene oxide - 3-Chloro-1-propene - A14330 - Alfa Aesar

A14330 Allyl chloride, 98%, stab. with propylene oxide

CAS Number
107-05-1
Synonyms
3-Chloro-1-propene

Size Price ($) Quantity Availability
100ml 22.05
500ml 34.86
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Allyl chloride, 98%, stab. with propylene oxide

MDL
MFCD00000984
EINECS
203-457-6

Chemical Properties

Formula
C3H5Cl
Formula Weight
76.53
Melting point
-135°
Boiling Point
44-46°
Flash Point
-28°(-18°F)
Density
0.939
Refractive Index
1.4155
Solubility
Soluble in water (3600 mg/L at 20°C), ethanol, ether, petroleum, acetone, chloroform, benzene, methanol and 2-prop.

Applications

Allyl chloride is used as an alkylating agent. It is used in treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene.

Notes

Store at -20°C. Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong oxidizing agents, boron trifluoride, sulfuric acid and nitric acid

Literature References

Kenji Uneyama.; Nobuyoshi Kamaki.; Akihiko Moriya.; Sigeru Torii. Tin(II)-aluminum-promoted allylation of aldehydes with allyl chloride in an aqueous solvent system. J. Org. Chem. 1985, 50 (25), 5396-5399.

Farley Fisher.; Douglas E. Applequist. Synthesis of 1-Methylcyclopropene. J. Org. Chem. 1965, 30 (6), 2089-2090.

Lithiation with LDA in THF at -78o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).

Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H341-H351-H373-H400-H302-H312-H332-H315-H319-H335

Highly flammable liquid and vapour. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P260-P201-P261-P273-P280-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,289
Beilstein
635704
Hazard Class
3
Packing Group
I
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
UC7350000

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