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A14330 Allyl chloride, 98%, stab. with propylene oxide

CAS Number
107-05-1
Synonyms
3-Chloro-1-propene

Stock No. Size Price ($) Quantity Availability
A14330-AE 100ml 25.50
A14330-AP 500ml 40.80
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Allyl chloride, 98%, stab. with propylene oxide

MDL
MFCD00000984
EINECS
203-457-6

Chemical Properties

Formula
C3H5Cl
Formula Weight
76.53
Melting point
-135°
Boiling Point
44-46°
Flash Point
-28°(-18°F)
Density
0.939
Refractive Index
1.4155
Storage & Sensitivity
Keep Cold.
Solubility
Soluble in water (3600 mg/L at 20°C), ethanol, ether, petroleum, acetone, chloroform, benzene, methanol and 2-prop.

Applications

Allyl chloride is used as an alkylating agent. It is used in treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene.

Notes

Store at -20°C. Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong oxidizing agents, boron trifluoride, sulfuric acid and nitric acid

Literature References

Kenji Uneyama.; Nobuyoshi Kamaki.; Akihiko Moriya.; Sigeru Torii. Tin(II)-aluminum-promoted allylation of aldehydes with allyl chloride in an aqueous solvent system. J. Org. Chem. 1985, 50 (25), 5396-5399.

Farley Fisher.; Douglas E. Applequist. Synthesis of 1-Methylcyclopropene. J. Org. Chem. 1965, 30 (6), 2089-2090.

Lithiation with LDA in THF at -78o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).

Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H302-H312-H315-H319-H332-H335-H341-H351-H373

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280i-P281-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P312-P330-P332+P313-P337+P313-P363-P37

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation occurs: If eye irritation persists: Wash contaminated clothing before reuse.

Other References

Merck
14,289
Beilstein
635704
Hazard Class
3
Packing Group
I
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
UC7350000

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